个人简介
Education
2002-2007: Ph.D., Dalian Institute of Chemical Physics,CAS (Advisor: Zhengkun Yu)
2005: Exchange Student, University of Ottawa (Advisor: Howard Alper)
2002-2003: Basic Courses Study, University of Science and Technology of China
1998-2002: B.S., Hubei University
Experience
2013-present: Full Professor, Sun Yat-Sen University
2010-2013: Post-Doctoral Fellow, Colorado State University (Advisor: Tomislav Rovis)
2008-2010: Post-Doctoral Fellow, University of Toronto (Advisor: Vy M. Dong)
个人简介
研究领域
不对称催化与合成，有机硒、硫小分子催化，有机氟化学
研究领域
专业：
研究方向：
研究领域和兴趣：
近期论文
Liang, Y.; Ji, J.; Zhang, X.; Jiang, Q.; Luo, J.; Zhao, X.* Enantioselective Construction of Axially Chiral Amino Sulfide Vinyl Arenes by Chiral Sulfide‐Catalyzed Electrophilic Carbothiolation of Alkynes. Angew. Chem. Int. Ed. 2020, DOI:10.1002/anie.201915470.
Wei, W.; Liao, L.; Qin, T.; Zhao, X.* Access to Saturated Thiocyano-Containing Azaheterocycles via Selenide-Catalyzed Regio- and Stereoselective Thiocyanoaminocyclization of Alkenes. Org. Lett. 2019, 21, 7846-7850.
Liang, Y.; Zhao, X.* Enantioselective Construction of Chiral Sulfides via Catalytic Electrophilic Azidothiolation and Oxythiolation of N-Allyl Sulfonamides. ACS Catal. 2019, 9, 6896-6902.
Li, H.; Liao, L.; Zhao, X.* Organoselenium-Catalyzed Aza-Wacker Reactions: Efficient Access to Isoquinolinium Imides and an Isoquinoline N-Oxide.Synlett 2019, 30, 1688-1692.
Cao, Q.; Luo, J.; Zhao, X.* Chiral Sulfide Catalysis for Desymmetrizing Enantioselective Chlorination. Angew. Chem. Int. Ed. 2019, 58, 1315-1319.
Qin, T.; Jiang, Q.; Ji, J.; Luo, J.; Zhao, X.* Chiral selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated 2,5-disubstituted oxazolines. Org. Biomol. Chem. 2019, 17, 1763-1766.
An, R.; Liao, L.; Liu, X.; Song, S.; Zhao, X.* Acid-catalyzed oxidative cleavage of S–S and Se–Se bonds with DEAD: efficient access to sulfides and selenides. Org. Chem. Front. 2018, 5, 3557-3561.
Xu, J.;# Zhang, Y.;# Qin, T.; Zhao, X.* Catalytic Regio- and Enantioselective Oxytrifluoromethylthiolation of Aliphatic Internal Alkenes by Neighboring Group Assistance.(# These authors contributed equally to this work) Org. Lett. 2018, 20, 6384–6388.
Liao, L.; Zhang, H.; Zhao, X.* Selenium-π-Acid Catalyzed Oxidative Functionalization of Alkynes: Facile Access to Ynones and Multisubstituted Oxazoles. ACS Catal. 2018, 8, 6745−6750.
Liu, X.; Liang, Y.; Ji, J.; Luo, J.; Zhao, X.* Chiral Selenide-Catalyzed Enantioselective Allylic Reaction and Intermolecular Difunctionalization of Alkenes: Efficient Construction of C-SCF3 Stereogenic Molecules.J. Am. Chem. Soc. 2018, 140, 4782−4786.
Luo, J.; Cao, Q.; Cao, X.*; Zhao, X.* Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation.Nat. Commun. 2018, 9, 527.
Guo, R.; Huang, J.; Zhao, X.* Organoselenium-Catalyzed Oxidative Allylic Fluorination with Electrophilic N–F Reagent. ACS Catal. 2018, 8, 926–930.
Zhu, Z.; Luo, J.; Zhao, X.* Combination of Lewis Basic Selenium Catalysis and Redox Selenium Chemistry: Synthesis of Trifluoromethylthiolated Tertiary Alcohols with Alkenes. Org. Lett. 2017, 19, 4940–4943.
Luo, J.; Liu, Y.; Zhao, X.* Chiral Selenide-Catalyzed Enantioselective Construction of Saturated Trifluoromethylthiolated Azaheterocycles. Org. Lett. 2017, 19, 3434–3437.
Guo, R .; Liao, L.; Zhao, X.* Electrophilic Selenium Catalysis with Electrophilic N-F Reagents as the Oxidants.Molecules 2017, 22, 835.
Liao, L.; Guo, R.; Zhao, X.* Organoselenium-Catalyzed Regioselective C-H Pyridination of 1,3-Dienes and Alkenes. Angew. Chem. Int. Ed. 2017, 56, 3201–3205.
Luo, J .; Liu, X.; Zhao, X.* Development of Chalcogenide Catalysts towards Trifluoromethylthiolation.Synlett 2017, 28, 397-401.
Wu, J.-J.; Xu, J.; Zhao, X.* Selenide-Catalyzed Stereoselective Construction of Tetrasubstituted Trifluoromethylthiolated Alkenes with Alkynes. Chem. Eur. J. 2016, 22, 15265–15269.
Liu, X.; An, R.; Zhang, X.; Luo, J.; Zhao, X.* Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide. Angew. Chem. Int. Ed. 2016, 55, 5846–5850.
近期论文
